The EU greenhouse gas (GHG) emissions reduction target is 55% by 2030. The EU building stock represents the largest single energy consumer accounting for 40% of energy consumption and 36% of EU GHG emissions.
Windows are the only components of a building that can modulate both free solar heat and natural indoor lighting. They are key to providing the desired thermal and lighting comfort to occupants, while minimise energy losses through the building fabric and lower energy consumption for heating, cooling and lighting. More than 30% of the building energy use is associated with windows.
Switchable Windows are chromogenic (optically switchable) devices that can switch between (i) a fully or partially absorptive state and (ii) a fully or partially reflective state resulting in modulation of light transmission. Dynamically adapting their thermal and light transmission properties they provide considerable energy savings and the desired indoor conditions. Benefits are listed in the ERBE theme box above.
Cost Barriers: Cost remains stubbornly high, with tungsten (WO3 ) devices ~€500/m2 to the end user without frame and control unit.
Performance Barriers: Organic polymeric electrochromic (EC) materials like PANI and PEDOT have peak to peak transmission modulation of 42-44%, with the fastest switching time (30 seconds) for small (4cm2 ) sample areas. Large transmission modulation over the visible and infrared light range using bilayer EC devices have been demonstrated. A large size (1200cm2 ) non-tungsten-based device using niobium pentoxide switches in 180 seconds.
EC devices have great advantages that if developments of appropriate ionic and electronic materials succeed at improving their switching cycle-ability this would make EC devices ideal switching devices. Other areas of improvement include the transmission modulation range and switching speed.
This project will design, simulate, prototype and characterise a novel lab-scale (~5x5cm2 ) low-cost organic electrochromic devices (ECD) using a range of electrochromic materials in conjunction with a novel Polymer Gel and/or similar conductive electrolytes. The research aims to tackle the cost and performance drawbacks of switchable windows namely by demonstrating 3-10 fold cost reduction compared to WO3 devices, increase life cycle of PEDOT ECD by 1 or 2 order of magnitude, increase transmission modulation range and faster switching speed.
Methodology and Scope
Polymer gel electrolytes (PGEs) beneficial properties are reasonable ionic conductivities, wide electrochemical potential windows, negligible volatility, increased charge-discharge cycle stability, improved Faradaic efficiency and substantially reduced sensitivity to moisture. They can be tailored to specific applications.
Deep Eutectic Solvents (DES) are a non-toxic, affordable subclass of ionic liquids. Apart from lower cost they are also characterized by simple one-pot synthesis with 100% atom economy.
Electrochemical performance of PEDOT/DES systems has been studied. PGE are a suitable source of dopants for PEDOT film with no degradation of polymeric films observed. We propose to extend this methodology to PGE’s based on DES electrolytes. Inexpensive electrolyte chemicals and ions doping PEDOT film are selected.
Electrochemical methods will be used to ascertain the performances of new electrochromic devices (ECD) such as cycling behaviour and stability. Spectroscopy and microscopy techniques will be used for surface characterisation and ascertain the transmittance characteristics over the visible and infrared light range.
Microgravimetric studies are key to determine the switching cycle-ability performances. A novel acoustic approach to investigate the redox behaviour of electrolytes will provide much accurate results compared to the typical Sauerbrey method.
Aims tackled by:
APPLY HERE: https://www.marei.ie/phd-positions-in-the-energy-resilience-in-the-built-environment-centre-for-doctoral-training-erbe-cdt/
Dr. Philippe Lemarchand, TU Dublin, Dublin Energy Lab
Professor John Cassidy, TU Dublin, Applied Electrochemistry Group
Dr. Sourav Ghosh, Loughborough University
Student Stipend € 18,500 p.a. (net/Tax free)
Equipment/Materials/ Travel/Training: €83,550
Fees € 5,500 p.a.
Funding category: Financement public/privé
PHD title: Doctorat in Ingenieurie , Engineering PhD
PHD Country: Irlande
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